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  • 1
    Digitale Medien
    Digitale Medien
    Solute-membrane interactions in hyperfiltration (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 1809-1822 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The performances of several composite membranes (PEC-1000, Teijin, HR-95, HR-98) and one asymmetric membrane (Solrox SC-200) in hyperfiltration are compared at 25°C using different aqueous feed solutions (0.1M and 0.5M NaCl, 0.5M 1,3-and 1,4-dioxan, 0.1M benzyl alcohol and 2-methoxybenzyl alcohol, 1,2- and 1,4-butandiol, and Triton feed solution). The effects of solute dissociation, polarization, and hydrogen bonding ability on solute permeability are discussed; steric effects are also being considered. Strong solute-membrane interactions are exhibited in hyperfiltration by systems with distinct hydrogen bonding capabilities of the solute with functional sites of the membrane matrix. Knowledge of solute-membrane interactions can be useful for elaborating separation and transport mechanisms.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1987.070330532
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  • 2
    Digitale Medien
    Digitale Medien
    A study on the plasma polymerization of some cyano-containing compounds and their electrical properties (1989)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 27 (1989), S. 3799-3809 
    Details
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Plasma polymerization of some cyano-containing organic compounds was carried out at 13.56 MHz from the gas phase. The resulting polymer films were smooth and pinhole free. The electrical conductivities of the polymer films varied from 10-12 to 10-7 S cm-1 depending upon which cyano-containing monomer was used. The Al/polymer film/ITO (indium-tin oxide) sandwich cells made from the films demonstrated a photovoltaic effect, and some of them showed good rectifying behavior. Infrared spectroscopy (IR) and ultraviolet spectroscopy (UV) were utilized to characterize the structure of the product polymers. The effects of the original structure in the starting monomers on the structure of the resulting polymers are investigated. The influence of incident light intensity on the photovoltaic characteristics was also investigated.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pola.1989.080271120
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  • 3
    Digitale Medien
    Digitale Medien
    Design of a system for the control of low dissolved oxygen concentrations: Critical oxygen concentrations for Azotobacter vinelandii and Escherichia coli (1985)
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 27 (1985), S. 151-155 
    Details
    ISSN: 0006-3592
    Schlagwort(e): Chemistry ; Biochemistry and Biotechnology
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Biologie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: The physiological activity of microorganisms in environments with low dissolved oxygen concentrations often differs from the metabolic activity of the same cells growing under fully aerobic or anaerobic conditions. This article describes a laboratory-scale system for the control of dissolved oxygen at low levels while maintaining other parameters, such as agitator speed, gas flowrate, position of sparger outlet, and temperature at fixed values. Thus, it is possible to attribute in dilute nonviscous fermentations all physiologic changes solely to changes in dissolved oxygen. Experiments were conducted with Azotobacter vinelandii and Escherichia coli. Critical oxygen concentrations for growth (that value of oxygen allowing growth at 97% of μmax) were measured as 0.35 ± 0.03 mg/L for A. vinelandii and 0.12 ± 0.03 mg/L for E. coli. These values are significantly different from the commonly quoted values for critical oxygen concentrations based on respiration rates. Because of the superior dissolved oxygen control system and an improved experimental protocol preventing CO2 limitation, we believe that the values reported in this work more closely represent reality.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/bit.260270208
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  • 4
    Digitale Medien
    Digitale Medien
    Particle contact dynamics on tubes in the freeboard region of fluidized beds (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1225-1227 
    Details
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/aic.690330720
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  • 5
    Digitale Medien
    Digitale Medien
    Surface tension of solid-liquid slurries (1987)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 316-318 
    Details
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/aic.690330220
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  • 6
    Digitale Medien
    Digitale Medien
    Influence of the wall on transient conduction into packed media (1985)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 168-170 
    Details
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/aic.690310124
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  • 7
    Digitale Medien
    Digitale Medien
    A heat transfer model for tubes immersed in gas fluidized beds (1985)
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 31 (1985), S. 244-252 
    Details
    ISSN: 0001-1541
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Notizen: A model for local heat transfer between a gas-fluidzed bed and a submerged tube is proposed based on combined dense-phase and lean-phase transport. The heat transfer process during dense-phase contact at the tube surface is modeled by packet renewal mechanism and the transfer process during lean-phase contact by fluid convection mechanism. The model predictions show good agreement with experimental local and average heat transfer coefficient data for horizontal tubes.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/aic.690310211
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  • 8
    Digitale Medien
    Digitale Medien
    Hydrogen bonding in polymer mixtures (1986)
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 24 (1986), S. 1597-1609 
    Details
    ISSN: 0887-6266
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Physik
    Notizen: The enthalpy-infrared frequency shift correlation for simple acids and bases is extended to study hydrogen bonding in polymer systems. The acidity of a polymer is calibrated by comparing the shifts in hydroxyl absorption frequency of the acidic polymer when mixed with a series of bases with the corresponding spectral shifts of known acids with the same bases. The basicity of a polymer is calibrated by measuring the hydroxyl frequency shifts of known acids when mixed with the basic polymer. For polymers containing carbonyl groups, the shift in carbonyl absorption is also a measure of basicity. The acidity and basicity constants obtained for polymers are in good agreement with the values for small-molecule analogs. The enthalpies of hydrogen bond formation in polymer mixtures are calculated from the acidity or basicity constants.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/polb.1986.090240716
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  • 9
    Digitale Medien
    Digitale Medien
    The determination of polymer interfacial tension by drop image processing: Comparison of theory and experiment for the pair, poly(dimethyl siloxane)/polybutndieneThis paper is dedicated to Prof. Bryce Maxwell on the occasion of his retirement from Princeton University (1986)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 1410-1418 
    Details
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The interfacial tensions of immiscible binary blends of poly(dimethyl siloxane) (PDMS) and polybutadiene (PBD) have been determined as a function of molecular weight and temperature. The technique employed for these measurements takes advantage of recent advances in the determination and analysis of pendant fluid drop profiles. The experimental data are compared to the predictions of square gradient theories and theories based on the diffusion equation approach as developed by Helfand and co-workers. Qualitative agreement is obtained with both types of theory when the Flory-Huggins interaction parameter is taken to be comprised of two terms: a temperature independent term of entropic origin; and an enthalpic term that is inversely dependent upon the temperature.
    Zusätzliches Material: 10 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pen.760262010
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  • 10
    Digitale Medien
    Digitale Medien
    Application of Matrix Algebra to Stoichiometry of a Chemical Reaction System and Dimensional Analysis (1988)
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 60 (1988), S. 483-486 
    Details
    ISSN: 0009-286X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Werkstoffwissenschaften, Fertigungsverfahren, Fertigung
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/cite.330600612
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