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  • 1985-1989  (2)
  • Extraction-spectrophotometric determination  (1)
  • isotachophoresis  (1)
  • Nuclear Reactions
  • Nuclear reactions
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  • 1985-1989  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Estimation of the critical micelle concentrations and the aggregation numbers of sodium alkyl sulfates by capillary-type isotachophoresis (1987)
    Springer
    Colloid & polymer science 265 (1987), S. 604-612 
    Details
    ISSN: 1435-1536
    Keywords: Criticalmicelle concentration ; aggregation number ; sodium alkyl sulfates ; isotachophoresis ; PU value
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The analytical procedure for the separation and quantification of bulk and micellar phases for sodium alkyl sulfates has been investigated by a capillary-type isotachophoresis using a potential gradient detector. Monomer solutions were distinguished from micellar solutions at pH 5.5–6.0; hydrochloric acid — L-Histidine mixture was used as the leading electrolyte and 2-(N-Morpholino) ethanesulfonic acid as the terminating electrolyte. The potential unit value (PU value) due to the monomer solutions was larger than that due to the micellar solutions. The zone length due to monomer solutions increased with increasing concentration of surfactant until a given concentration (CMC); beyond this point the values became constant. On the other hand, the zone length due to micellar solutions increased from this point. We report an applicability of capillary-type isotachophoresis to determination of the CMC's and aggregation number for various sodium alkyl sulfates.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01412776
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Distribution measurement of sodium octyl sulfate in multiphase microemulsion based on the extraction-spectrophotometric method (1988)
    Springer
    Colloid & polymer science 266 (1988), S. 475-478 
    Details
    ISSN: 1435-1536
    Keywords: Extraction-spectrophotometric determination ; anionic surfactant ; phase transition ; multiphase microemulsion systems
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The determination of anionic surfactant contents in multiphase microemulsions, based on the extraction-spectrophotometric method, has been carried out. The multiphase microemulsion system we studied is composed of sodium octyl sulfate (SOS), n-hexanol, n-decane, and brine. The system shows Winsor type phase-transitions (Winsor I type ↔ Winsor III type ↔ Winsor II type) with changing salinity. We found that the extraction-spectrophotometric method used here is very useful for the determination of anionic surfactants in any microemulsion phases: the partition ratios of SOS in two different phases change continuously within the salinity region at which the phase transition takes place.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF01457266
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
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