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  • 1
    ISSN: 1573-1561
    Keywords: Fire bee ; Trigona (Oxtrigona) mellicolor ; Trigona (Oxtrigona) tataira ; honeybee ; Apis mellifera ; Hymenoptera ; Apidae ; mandibular gland secretion ; allomone ; nest plundering ; diketones ; (E)-3-heptene-2,5-dione ; (E)-3-nonene-2,5-dione
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Ten volatile compounds derived from the cephalic glands of the fire beeTrigona (Oxytrigona)mellicolor were bioassayed for possible allomonal activities facilitating nest plundering. Two diketones, (E)-3-heptene-2,5-dione and (E)-3-nonene-2,5-dione, caused the honeybeeApis mellifera to display avoidance behavior and reduced defensive behavior. These diketones are produced in relatively large quantities in fire-bee cephalic glands.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0878
    Keywords: Androgen ; Estrogen ; Pituitary gland ; Male genital tract ; Rhesus monkey, Macaca mulatta (Primates)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Target cells for testosterone, dihydrotestosterone, and estradiol in the pituitary gland and genital tract of the male primate were localized by thaw-mount autoradiography, and high performance liquid chromatography was used to identify the metabolites of these steroids in cell nuclei. Castrated rhesus monkeys were injected with 3H-testosterone, 3H-dihydrotestosterone, or 3H-estradiol and killed 60 min later. In the anterior pituitary gland, fewer cells were labeled and less radioactivity was taken up by cell nuclei following the administration of either 3H-testosterone (4% of pars distalis cells and 5 dpm/μg DNA) or 3H-dihydrotestosterone (5% of cells and 13 dpm/μg DNA) than following the administration of 3H-estradiol (43% of cells and 214 dpm/μg DNA). Most of the radioactivity in nuclei was in the form of the unmetabolized parent compound (78–94%). In prostate, seminal vesicles, and penis, 3H-dihydrotestosterone was the predominant form of nuclear radioactivity following both 3H-testosterone (67–90%) and 3H-dihydrostestosterone (94–97%) administration, and both androgens labeled epithelial and smooth muscle cells. In contrast, 3H-estradiol was taken up in unchanged form, by cell nuclei of the genital tract and it labeled connective tissue fibroblasts, but not epithelial cells. Thus, the distributions of target cells for androgens and estrogens were clearly different in all these tissues, and the uptake of testosterone resembled that of its androgenic rather than that of its estrogenic metabolite.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical ecology 10 (1984), S. 451-461 
    ISSN: 1573-1561
    Keywords: Fire bee ; Trigona (Oxytrigona) tataira ; Hymenoptera ; Apidae ; mandibular gland secretion ; enediones ; monoketones ; carboxylic esters ; hydrocarbons ; E-3-hepten-2,5-dione ; E-3-nonen-2,5-dione
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Analysis of the volatile compounds derived from cephalic glands of the fire beeTrigona (Oxytrigona) tataira by GC-MS was undertaken. The following compounds were readily identified: hydrocarbons:n-C11H24,n-C13H28,n-C14H30,n-C15H32,n-C17H36,n-C23H48,n-C15H30,n-C17H34,n-C21 H42, andn-C23H46; carboxylic acids: palmitic acid, linoleic acid, linolenic acid, stearic acid, and oleic acid; carboxylic esters: dodecyl acetate, tetradecyl acetate, hexadecyl acetate, octadecyl acetate, and dodecyl decanoate; monoketones: 5-hepten-2-one, 3-hepten-2-one, 2-heptanone, and 5-nonen-2-one. Two major components of the mixture were identified asE-hepten-2,5-dione andE-3-nonen-2,5-dione. Structures of these novel compounds were suggested by their GC-MS behavior and the GC-MS behavior of their dimethoximes and proved by comparison with authentic synthetic samples. Trace amounts of the corresponding Z isomers and the saturated analogs, heptan-2,5-dione and nonan-2,5-dione, were also found. The possible functions of these glandular constituents are discussed.
    Type of Medium: Electronic Resource
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