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Chemistry of the Silicon-Silicon Double Bond (1987)

West, Robert

Weinheim : Wiley-Blackwell

Angewandte Chemie International Edition in English 26 (1987), S. 1201-1211

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ISSN: 0570-0833

Schlagwort(e): Multiple bonds ; Disilenes ; Chemistry ; General Chemistry

Quelle: Wiley InterScience Backfile Collection 1832-2000

Thema: Chemie und Pharmazie

Notizen: Disilenes, compounds containing silicon-silicon double bonds, can be isolated as thermally stable, yellow- or orange-colored crystalline compounds; the substituent groups at silicon must be large (mesityl, tert -butyl, etc.) to prevent polymerization. Structural and spectro-scopic studies indicate many similarities between the 3p-3p π bonding in disilenes and the 2p-2p π bonding in olefins, but disilenes are much more reactive than alkenes. The reactions of disilenes lead to many new classes of silicon compounds, including three- and four-membered rings which present novel problems in chemical bonding.

Zusätzliches Material: 9 Ill.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1002/anie.198712013

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