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On the validity of the Mark-Houwink relationship at very high molecular weights (1989)

Barham, P. J. ; Keller, A.

Springer

Colloid & polymer science 267 (1989), S. 494-499

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ISSN: 1435-1536

Keywords: Polystyrene ; (M w≳106) ; intrinsic viscosity ; adsorption-entanglementlayers ; toluene ; decaline

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics

Notes: Abstract Adsorption-entanglement layers have been shown to interfere with the measurement of intrinsic viscosity of high-molecular weight (M w≳106) atactic polystyrene solutions. Values of the intrinsic viscosity, corrected for the pressure of any such layers are reported. The Mark-Houwink relationship is thus shown to fail at high molecular weights.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01416054

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