ISSN:
0749-1581
Keywords:
1-phenyl- and 1-cyano-substituted
;
3,3-dimethyl-2-thiatricyclo[3.2.1.16,8]nonane
;
2,2-dioxide
;
13C and 1H 2D NMR
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Total assignment of 13C and 1H NMR spectra of the new compounds 1-cyano- and 1-phenyl-substituted 3,3-dimethyl-2-thiatricyclo[3.2.1.16,8]nonane 2,2-dioxide was achieved using the concerted application of two-dimensional homonuclear and heteronuclear chemical shift correlations. This unequivocal structure determination rules out the formation of a six-membered ring during the intramolecular cyclization of the α-sulphonyl-C centred radical originating from 5-endo-isopropylsulphonyl-5-exo-substituted norbornene.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260250506
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