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  • 1985-1989  (3)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 32 (1986), S. 4263-4269 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The molecular weight distribution (MWD) of bulk ultrahigh molecular weight polyethylene (UHMWPE) was determined by an increasing temperature sequential extraction technique. Using decahydronapthalene (decalin) as the solvent, 5 g samples of UHMWPE were fractionated stepwise from room temperature to 190°C in 10°C increments. Results via high temperature capillary viscometry show that intrinsic viscosity ([η]) ranges from 12.0 to 37.0 dL/g or that the viscosity average molecular weight (M̄v) ranges from approximately 1.6 to 7.4 × 106. When the integral distribution is plotted against M̄v on logarithmic probability graph paper, a straight line (i.e., a Wesslau distribution) results. Although the present methodology is tedious, many previous problems which have led to degradation are overcome by this technique.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Biomedical Materials Research 19 (1985), S. 35-55 
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: Because replicate materials have requirements different from those of recording or impression materials, quantitative methodologies were sought using commercial impression materials. Two satisfactory objective techniques resulted, a laser-scattering and a capillary flow test. Using high-resolution gratings to simulate tooth detail (〈1 μm), the reproduction quality of 36 two-stage replicas was determined in diffraction, reflection, and in an unblazed state. Using precision bore glass tubes (0.25, 0.5, 1, and 2 mm diameters) to simulate the high-energy surface of enamel, the flow characteristics of nine elastomers (the first stage replicates) and four epoxies (the second stage replicates) were determined at isobaric conditions. Because the laser spot size was relatively large (0.6 mm) and the pressure differential was small (25 mm Hg), both the global resolution and the low shear rate characteristics could be measured. Of the commercial materials tested, Reprosil Light had the best combination of fluidity and resolution, regardless of which positive material was used. Although Permagum Low, Silene Wash, and Xantopren Blue scored high in one of the two tests, none of these materials could compare to Reprosil Light within the context described herein.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0021-9304
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Medicine , Technology
    Notes: A bulk ultra-high molecular weight polyethylene product, IMPAX 5M+ UHMW-NAT, was fractionated using an increasing-temperature sequential-extraction technique. In the presence of an inert atmosphere and an antioxidant, 5 g of material were methodically dissolved in decahydronaphthalene over the temperature range, 80-191°C. Initially, intrinsic viscosities were measure in decalin at 135°C by single point capillary viscometry. From this data the viscosity average molecular weights were estimated using a logarithmic expression. Results showed that the intrinsic viscosities (molecular weights) increased linearly with extraction temperature over a range from 10 to 40 dL/g (1 to 8 × 106) and that the molecular weight distribution was log normal. Mass balances both before and after extraction indicated that less than 0.3% of the material had a molecular weight less than 106 and that less than 0.1% of the material was gel. Zero shear viscometry of bulk fractionated polymer and powdered whole polymers confirmed that capillary viscometry increasingly under-estimates the true intrinsic viscosities as the polymer chain lengths (molecular shear forces) increase. Indeed, the actual molecular weights ranged from about 2-14 × 106. Knowledge of the molecular weight distribution of bulk products and the presence of either volatiles or crosslinked networks is critical for the continued design and development of superior wearing and fatigueresistant implants.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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