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  • 1980-1984
  • 1975-1979  (2)
  • 1950-1954
  • branching ratio  (1)
  • inelastic relaxation  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 14 (1976), S. 469-481 
    ISSN: 1572-9613
    Keywords: Chemical kinetics ; nonequilibrium statistical mechanics ; correlation functions ; Boltzmann equation ; Chapman-Enskog solutions ; inelastic relaxation ; projection operator
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The relaxation of an internal state distribution in the presence of an excess of an inert gas is considered. The explicit time dependence of the nonequilibrium contributions to the transition rate coefficients is approximated using the Kapral-Hudson-Ross method. The resulting solution contains cross-correlation terms which do not appear when a single reaction is considered. It is shown that the first term of a perturbation expansion of an exact formal solution gives the Kapral-Hudson-Ross solution for short times, and the Chapman-Enskog solution at long times if there is a wide separation in time scales. The Kapral-Hudson-Ross, Chapman-Enskog, and exact solutions are compared for a two-state, hard-sphere model system.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of statistical physics 19 (1978), S. 525-541 
    ISSN: 1572-9613
    Keywords: Random walks ; stochastic processes ; exponential models ; mean first passage time ; branching ratio
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract We present here exact analytic results for a random walk on a one-dimensional lattice with asymmetric, exponentially distributed jump probabilities. We derive the generating functions of such a walk for a perfect lattice and for a lattice with absorbing boundaries. We obtain solutions for some interesting moment properties, such as mean first passage time, drift velocity, dispersion, and branching ratio for absorption. The symmetric exponential walk is solved as a special case. The scaling of the mean first passage time with the size of the system for the exponentially distributed walk is determined by the symmetry and is independent of the range.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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