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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 21 (1982), S. 308-319 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 17 (1978), S. 875-879 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Naturwissenschaften 71 (1984), S. 171-180 
    ISSN: 1432-1904
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology , Natural Sciences in General
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 438 (1978), S. 53-67 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On BiBr and BiBr1,167Preparation and crystal structures of BiBr1,167 and BiBr are describe as well as their phase relationships. BiBr1,167 is isotypic with the familiar BiCl1,167, the structures comprising the cluster Bi95+ with the same Bi—Bi distances and deviations from trigonal symmetry. A simple electrostatic attraction-repulsion calculation with respect to the stability of the particular cluster configuration is given. The structure of BiBr consists of infinite onedimensional chains ∞1[Bi4Br4] as the structure of BiI. These compounds are structurally classified as special stacking variants of a common motif.
    Notes: Es werden Darstellung und Kristallstrukturen der niederwertigen Wismutbromide BiBr1,167 und BiBr sowie ihr phasenanalytischer Zusammenhang beschrieben. Die Verbindung BiBr1,167 ist isotyp zu dem bereits bekannten BiCl1,167 und enthält wie dies den Wismut-Cluster Bi95+, mit den gleichen Abstandsverhältnissen und Abweichungen von der trigonalen Symmetrie. Es wird eine einfache Modellrechnung zur Stabilität der Konfiguration angegeben. Die Verbindung BiBr ist wie BiJ aus unendlichen eindimensionalen ∞1[Bi4Br4]-Verbänden aufgebaut. Es wird eine Systematik angegeben, diese Verbindungen als Stapelvarianten desselben Grundmuster einzuordnen.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 431 (1977), S. 5-16 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On Alkali Metal Suboxides. 11. The “Complex Metal” Rb9O2Preparation and crystal structure of the copper-coloured rubidium suboxide Rb9O2 are described. The compound consists of ion clusters of identical composition with metallic bonding between the clusters.By comparison of X-ray data it is shown, that Rb9O2 is the main component of a suboxide described as “Rb3O” before.
    Notes: Darstellung und Kristallaufbau für das kupferrote Rubidiumsuboxid Rb9O2 werden beschrieben. Die Verbindung besteht aus Ionengruppen der gleichen Zusammensetzung, die metallisch aneinander gebunden sind. Durch Vergleich der Röntgendaten wird nachgewiesen, daß der Hauptanteil des mehrfach als „Rb3O“ beschriebenen Suboxids mit Rb9O2 identisch ist.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 486 (1982), S. 7-21 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Properties and Crystal Structures of Reduced Gallium Halides: Ga2I4 and Ga2I3The compounds Ga2I4 and Ga2I3 were prepared as small single crystals by heating the elements in sealed glass ampoules. Thermal behaviour, IR and Raman spectra as well as the crystal structures were investigated. Due to our investigations Ga2I3 is the most metal-rich gallium iodide. According to X-ray results it is identical with the formerly described „GaI“. - The crystal structures of the compounds Ga2I4 and Ga2I3 were solved on the basis of diffractometer data: Ga2I4 forms rhombohedral crystals, space group R3c; a = 2 521.5(2) and c = 783.9(1) pm. The structure corresponds to the expected formula Ga+(GaI4)-. Tube-like arrangements of the GaI4 tetrahedra are the remarkable structural feature. These are bonded to one another by van der Waals forces and contain the Ga+ ions inside. This arrangement results from a (radial) close-packing of the I atoms of the GaI4- anions. Interstitials in this arrangement are occupied by Ga+-ions and modified in a way to show the influence of the non-bonding electron pair of the Ga+ ion. - Ga2I3 crystallizes in the monoclinic space group P21/c (a = 1 129.4(3); b = 871.5(1); c = 1 345.3(4) pm; β = 145.6(1)°) according to the formula (Ga+)2(Ga2I6)2-. The anion is isoelectronic (and isostructural) with Si2I6 and occurs in the staggered conformation. The Ga-Ga-distance is 238.7(5) pm. The coordination around Ga+ is very similar to that in Ga2I4.
    Notes: Die Verbindungen Ga2I4 und Ga2I3 wurden durch Reaktionen der Elemente in verschmolzenen Glasampullen in Form kleiner Einkristalle dargestellt. Thermische Eigenschaften, schwingungsspektroskopisches Verhalten und Strukturen wurden untersucht. Insbesondere wurde sichergestellt, daß Ga2I3 das metallreichste Galliumiodid im System Ga/I2 ist; Ga2I3 ist mit dem früher beschriebenen „GaI“ identisch. Ga2I4 kristallisiert rhomboedrisch in der Raumgruppe R3c mit a = 2521,5(2) und c = 783,9(1) pm. Der Aufbau entspricht erwartungsgemäß der Formel Ga+(GaI4)-. Auffallendes Strukturmerkmal sind röhrenförmige Anordnungen der GaI4-Tetraeder, die über van-der-Waals-Bindungen mit benachbarten Röhren zusammenhängen und die Ga+-Ionen im Inneren enthalten. Dieser Aufbau resultiert aus einer innerhalb der Röhren dichtesten Anordnung der I-Atome der GaI4-Anionen. Die Lücken dieser Anordnung sind durch Ga+-Ionen besetzt und lassen den Einfluß des nichtbindenden Elektronenpaars am Ga+-Ion erkennen. - Ga2I3 kristallisiert monoklin in der Raumgruppe P21/c mit a = 1 129,4(3); b = 871,5(1), c = 1 345,3(4) pm; β = 145,6(1)° und ist als (Ga+)2(Ga2I6)2- zu formulieren. Das mit Si2I6 isoelektronische (und isostrukturelle) Anion liegt in der gestaffelten Konformation vor; der Ga-Ga-Abstand beträgt 238,7(5) pm. Die Koordination von Ga+ entspricht weitgehend der in Ga2I4.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 88 (1976), S. 685-686 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie in unserer Zeit 10 (1976), S. 1-9 
    ISSN: 0009-2851
    Keywords: Chemistry ; Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 111 (1978), S. 1670-1676 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The Crystal Structure of 5-Oxo-1,3λ4,2,4-dithiazole, S2N2CO, and its Adducts with Lewis AcidsA simple synthesis of 5-oxo-1,3λ4,2,4-dithiadiazole (S2N2CO, 1) is reported. 1 crystallizes in the space group Pbca-D-2n15 and is a five-membered planar ring. Reactions of 1 in CH2Cl2 with the Lewis acids A yield the mono- and bisadducts S2N2CO · A and (S2N2CO)2 · A, where A = BF3 (2a), SO3 (2b), SbCl5 (2c), SbF2Cl3 (2d), SnCl4 (3a), and TiCl4 (3b). IR and Raman spectra are reported and possible structures of the adducts are discussed.
    Notes: Es wird eine einfache Synthese für 5-Oxo-1,3λ4,2,4-dithiadiazol (S2N2CO. 1) beschrieben. 1 kristallisiert in der Raumgruppe Pbca-D2n15 und ist ein fünfgliedriger planarer Ring. Reaktionen von 1 in CH2Cl2 mit den Lewis-Säuren A ergeben die Mono- und Bisaddukte S2N2CO · A und (S2N2CO)2 · A, wobei A = BF3 (2a), SO3 (2b), SbCl5 (2c), SbF2Cl3 (2d), SnCl4 (3a) und TiCl4 (3b) ist. IR- und Raman-Spektren werden mitgeteilt und mögliche Strukturen der Addukte diskutiert.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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