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  • 1980-1984  (2)
  • 1970-1974
  • Alkene separation  (1)
  • Clean water as mobile phase  (1)
  • 1
    ISSN: 1612-1112
    Keywords: Alkenes ; Gas-solid chromatography ; Ion exchangers ; Alkene separation ; Selectivity ; Specific interactions
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary The gas chromatographic selectivity of K+, Zn2+, Ag+, Ni2+, and Cd2+ forms of a cation exchange packing have been determined for a set of 44 C2 to C8 alkenes. The retention characteristics of each ion are broken down into electronic (charge-transfer) and steric effects associated with the alkene sub-populations of each carbon number. Almost every pair of alkenes tested can be separated on at least one of these packings. Retention is much stronger on the ion exchangers than on metal-ion containing packings in gas-liquid chromatography, even with shorter columns and higher temperatures.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Journal of High Resolution Chromatography 4 (1981), S. 280-286 
    ISSN: 0935-6304
    Keywords: Liquid chromatography ; Use of flame ionization detector ; Clean water as mobile phase ; Process analysis possibilities ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thermal Aqueous Liquid Chromatography (TALC) using pure water as a mobile phase should be a very attractive technique promoting the use of liquid chromatography in routine analysis, either in the laboratory or in future on-line process control. This simple form of chromatography, the selectivity of which depends on the fixed phase only, would allow the use of flame ionization as an almost universal, low-cost detector in liquid chromatography. The potential of the TALC technique is illustrated by selected examples.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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