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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 9 (1980), S. 123-125 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A simple equation relating the intensity of characteristic X-ray lines to their respective weight fractions has been obtained for a thick sample excited by an isotopic source. It follows from the equation that a single intense line in a standard sample suffices to generate calibration constants over a wide range of elements. Validity of this aproach has been demonstrated by the analysis of a standard soil sample using only the Fe Kα line for calibration. A procedure for correction of peak overlaps has been given using the Kβ/Kα ratios, modified by the matrix effects. The method is very useful for the analysis of soil samples and can be conveniently applied to other matrices.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 10 (1981), S. 180-186 
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: An attempt has been made to obtain theoretically the overlap coefficients of interfering lines in XRF spectra. The peaks have been analytically represented by a Gaussian function and the overlap evaluated for Covell integration. The coefficients for a wide range of elements and for various detector resolutions have been computed as a function of integration window width. The variation with window width of evaluated coefficients is compared with published experimental values.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 468 (1980), S. 228-230 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Thionitrosyl-Komplexe des Rhodiums(NSCl)3 reagiert mit Rhodium(I)-Komplexen bzw. mit RhCl3 · 3H2 in Gegenwart von Triphenylphosphin und Triphenylarsin unter Bildung von Thionitrosyl- and Carbonylthionitrosyl-Komplexen. Sie wurden durch Analyse, magnetische Messungen und IR-Spektren charakterisiert.
    Notes: (NSCl)3 reacts with Rhodium(I) complexes and with RhCl3 · 3H2O in the presence of triphenylphosphine and triphenylarsine to give thionitrosyl and carbonyl thionitrosyl complexes which are characterised by elemental analyses, magnetic measurements are i.r. spectra.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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