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Lattice vibrations of crystalline titanium and tin tetrachlorides (1984)

Tse, W. S. ; Liang, N. T. ; Chen, C. C. ; [et al.]

Chichester [u.a.] : Wiley-Blackwell

Journal of Raman Spectroscopy 15 (1984), S. 51-54

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Details

ISSN: 0377-0486

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The vibrational spectra of polycrystalline samples of titanium and tin tetrachlorides at 80 K have been investigated by Raman spectroscopic techniques. In the intramolecular region, isotopic and crystalline field splittings are observed, in substantial agreement with earlier work. In the lattice region, ten of the twelve Raman-active lattice modes are observed. A simple model is suggested and used to distinguish the low-frequency lattice translational from librational modes.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/jrs.1250150112

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