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  • 1980-1984  (2)
  • Inorganic Chemistry  (2)
  • Arsonium salts
  • Calculations, ab initio
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Year
Keywords
  • Inorganic Chemistry  (2)
  • Arsonium salts
  • Calculations, ab initio
  • Chemistry  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 114 (1981), S. 3737-3739 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The Formation of Trichlorosulfonium (IV) Hexafluoroarsenate(V)Sulfur reacts with chlorine and arsenic Trifluoride under pressure to give [SCl3]+[AsF6]-. As an intermediate oxidizing substance [AsCI4]+ is identified by spectroscopy. Depolarization-Raman-spectra confirm the assignment made in literature.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 506 (1983), S. 178-184 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the Preparation of Arsenic Dichloride Trifluoride, AsCl2F3AsCl2F3 is prepared by pyrolysis of [AsCl4]+ [AsF6]-. The vibrational spectra of the new low temperature compound are reported and the valence force constants are calculated. The formation of AsCl2F3 by ligand exchange reactions is discussed.
    Notes: AsCl2F3 wird durch Pyrolyse von [AsCl4]+ [AsF6]- präparativ dargestellt. Es werden die Schwingungsspektren der neuen Tieftemperaturverbindung gemessen und ihre Valenzkraftkonstanten berechnet. Die auf Ligandenaustauschreaktionen beruhende Bildung wird diskutiert.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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