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  • 1980-1984  (3)
  • Carbene rotational barriers  (2)
  • Golgi-vesicles  (1)
  • DNA ploidy
  • Gene expression
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Theoretical chemistry accounts 64 (1984), S. 461-467 
    ISSN: 1432-2234
    Keywords: Carbene rotational barriers ; Isolobal analogy ; Ab-initio SCF calculations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract LCAO-MO-SCF calculations are reported for the different stereoisomers of the Mo(CO)4(CH2)2 and Mo(CO)4[C(NH2)2]2 systems. The substitution of the hydrogen atoms by the amino groups in the carbene ligands leads to an almost zero rotational barrier. Steric interactions are therefore expected to govern the barrier for diaminocarbene ligands which are more bulky than C(NH2)2. The rotational isomerism in thesebis carbene MoL4 systems is also discussed in connection with the isolobal analogy between CH2 and C2H4.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Theoretical chemistry accounts 64 (1984), S. 461-467 
    ISSN: 1432-2234
    Keywords: Carbene rotational barriers ; Isolobal analogy ; Ab-initio SCF calculations
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract LCAO-MO-SCF calculations are reported for the different stereoisomers of the Mo(CO)4(CH2)2 and Mo(CO)4[C(NH2)2]2 systems. The substitution of the hydrogen atoms by the amino groups in the carbene ligands leads to an almost zero rotational barrier. Steric interactions are therefore expected to govern the barrier for diaminocarbene ligands which are more bulky than C(NH2)2. The rotational isomerism in thesebis carbene MoL4 systems is also discussed in connection with the isolobal analogy between CH2 and C2H4.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    ISSN: 1615-6102
    Keywords: Golgi-vesicles ; Myrmicacin ; Pollen tube ; Protoplasmic movement
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Summary While tube elongation of growing pollen ofCamellia japonica was stopped by treatment with 50–100 ppm of myrmicacin, protoplasmic movement in the pollen tube still continued. However, higher concentration (200 ppm) of the inhibitor arrested the movement. The vesicles containing membrane substances disappeared at the tip of the tube of the growth-inhibited pollen. Removal of the inhibitor resulted in the reappearance of the vesicles at the tip region and tube elongation was restored.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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