Electronic Resource
New York, NY
:
Wiley-Blackwell
International Journal of Chemical Kinetics
13 (1981), S. 1227-1233
ISSN:
0538-8066
Keywords:
Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The equilibrium I2(g) + 2NO(g) = 2INO(g) has been studied at room temperature by ultraviolet absorption spectroscopy. The equilibrium constant has been measured as Kp = (2.7 ± 0.3) × 10-6 atm-1 at 298 K. Third-law calculations lead to ΔH°f,298 (INO) = 120.0 ± 0.3 kJ/mol. The relative absorption spectrum of INO has been measured between 225 and 300 nm. Quantitative measurements gave ∊(λmax = 238 nm) = (1.79 ± 0.5) × 104 L/mol·cm and ∊(410 nm) = 234.7 ± 21 L/mol·cm.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/kin.550131203
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