ISSN:
0021-8383
Schlagwort(e):
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
Syntheses and Properties of Mono- and Disubstituted Monothio-β-dicarbonyl Compounds and their Nickel(II) chelatesReaction of phenylacetaldehyde with phosphorous oxichloride and dimethylformamide yielded 3-chloro-2-phenyl-propenal, which was converted into 2-phenyl-monothiomalonic dialdehyde 2 by treating with sodium sulfide nonahydrate. Furthermore the reactions of other mono- and diphenylsubstituted monothio-β-dicarbonyl compounds with aniline on the one side and nickel(II)acetate on the other side have been studied. It was shown, that compounds 1-6 react in different way with aniline yielding either sulfur free products or in case of 1 and 4 enaminothioketones, which are of interest as building blocks for syntheses.In contrast to this the nickel complexes of 1-6 indicates an one another similar, typical chelate structure, which have been elucidated by u.v.-vis-, i.r.- and x-ray photoelectron spectroscopy.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/prac.19823240213
Permalink