ISSN:
0001-1541
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Process Engineering, Biotechnology, Nutrition Technology
Notes:
Diffusion coefficients of argon, krypton, xenon, methane, carbon tetrachloride and the tetraalkyltins (methyl through butyl) were measured in methanol, 1-butanol and 1-octanol over the temperature range 298 to 433 K. With temperature-dependent solvent diameters fitted from the tracer diffusivity of one of the solutes, a rough-hard-sphere theory predicts well the observed tracer diffusivity over the solvent density range in which hard-sphere computer simulations are available. The Wilke-Chang correlation predicts diffusion coefficients in the higher alcohols with an average error of 80% and a maximum error of 200%. A correlation of the form Dμp/T = A where p and A depend on solute and solvent size is more successful giving an average error of 7% and a maximum error of 24%.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/aic.690290418
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