ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Binuclear organometallic palladium complexes of the general formulae Pd2[μ-(N-N′)]R2L4(ClO4)2 and Pd2[μ-(N-N′)]Cl2R2L2 [R = C6F5 or C6CI5; L = group VB or VIB ligand; (N-N') = 4,4′-bipyridine] have been prepared by reacting the ligand (N-N′) with compounds of the type Pd2(μ-CI)2R2L2 or PdOClO3RL2. Furthermore, polynuclear [PdR2(N-N′)]x (R = Cl, C6F5 or C6Cl5) type complexes have been obtained by reaction of the ligand (N-N′) with PdR2(tht)2, whilst treatment of [Pd2(μ-CI)2(C6F5)4](NBu4)2 with an excess of (N-N′) leads to the polynuclearcis-[Pd(C6F5)z(N-N′)]x species. Evidence for the structure of these compounds is obtained from their i.r. spectra.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01396939
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