ISSN:
0032-3888
Keywords:
Chemistry
;
Chemical Engineering
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
The Fluid-Lattice Theory (Ising Fluid), recently tested by Lacombe and Sanchez, has been modified by introducing the typical Flory's surface-to-volume ratio of the characteristic-segment of a polymeric liquid. This surface-to-volume ratio is not an adjustable parameter. It is obtained from Bondi's tabulations. The resulting new equation of state has three adjustable parameters per component and it represents a definite improvement for the fitting of P-V-T data for polymeric liquids. Extension to mixtures is not tested in this work but, in principle, it can be done by well-established methods.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pen.760220603
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