ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Summary Donor or acceptor groups and particularly capto-dative substituants determine the ease of selective hydrogen abstraction but steric factors and the nature of the dehydrogenating agent influence the relative “radical scale”. This study underlines the preparative value of dehydrodimerisations. This method allows in addition the preparation of oligomers and polymers. A continuation of this work will be published in the near future. The industrial synthesis of indigo by dehydrodimerisation of oxindol is a classical example of radical coupling(10) as a reaction type on which this publication focusses:
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF01064366
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