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Deactivation of I(52P1/2) by CF3I, CH3I, C2H5I, and CH4 (1984)

Gu, Z-N. ; Young, A. T. ; Houston, P. L.

New York, NY : Wiley-Blackwell

International Journal of Chemical Kinetics 16 (1984), S. 669-677

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ISSN: 0538-8066

Keywords: Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The technique of laser photolysis of alkyl and perfluoroalkyl iodides at 266 nm followed by time-resolved detection of the 1.3-μm emission from I*(2P1/2) has been used to measure the rate constants for deactivation of I* by CH3I, C2H5I, CF3I, and CH4. The recommended values are (2.76± 0.22) × 10-13, (2.85 ± 0.40) × 10-13, (3.5 ± 0.5) × 10-17, and (7.52 ± 0.12) × 10-14, respectively, in units of cm3 molecule-1 S-1.

Additional Material: 6 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/kin.550160605

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