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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 487-496 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A mar-resistant coating system was obtained by screening combinations of silicone and vinyl compounds. It was found that binary systems, such as the γ-glycidoxypropyltrimethoxysilane-glycidyl methacrylate system, were excellent not only in mar resistance but also in adhesion to base resin polymers. Haze values of these coatings, after the sand-falling test, reached less than 10%. The coating process consisted of three steps: the preparation of prepolymer, the coating to plastic surface, and the curing of the coating by heating. It was found that the prepolymerization step could be performed by irradiation very conveniently; the control of viscosity for coating application and thickness control could be possible without any gel formation. These coatings were also good in weather resistance due perhaps to the good adhesion to base resin and could be applicable to plastic spectacles, glazing materials, and a variety of other products.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 24 (1979), S. 235-247 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Compositions for good antifogging and mar-resistant coatings were investigated. A mixture of hydrolyzed aminoalkylalkoxysilane and hydrophilic vinyl monomer was the best combination. Control of suitable viscosity for coating was carried out conveniently by irradiation. The prepolymer was coated and cured by heating to form an antifogging membrane on various base materials such as inorganic glass, CR-39 resin, and poly(methyl methacrylate). These conditions were studied in relation to some physical properties of the membrane. It was found that antifogging and mar-resistant properties were inconsistent in many cases. A possible way to achieve the best balance between the two properties is discussed.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 823-832 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: It was previously reported that excellent mar resistance coating systems could be obtained by the combination of silicone compounds and vinyl compounds, such as KBM 403-GMA systems. Radiation-induced polymerization was the most efficient means of prepolymerization of give the viscosity suitable for coating. In this report, change in conversion and the predominant mechanims of prepolymerization were investigated by measuring the change in refractive index. It was shown that the conversion change and the predominant prepolymerization mechanism could be identified by the refractive index. The relationship between the refractive index and coating properties such as film thickness and haze value was also studied. Dripping of GMA prepolymer occurred, and coating thickness was small in GMA including prepolymer systems obtained predominantly by radical mechanism; the thickness was relatively large in the prepolymer systems obtained by epoxy ring opening-type polymerization mechanism. However, the mar resistance in the former was excellent in spite of reduced thickness.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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