Bibliothek

Notizen: Abstract The hyperfine structure (hfs) of the metastable atomic states 3d64s6 D 1/2, 3/2, 5/2, 7/2, 9/2 of55Mn was measured using theABMR- LIRF method (atomicbeammagneticresonance, detected bylaserinducedresonancefluorescence). The hfs constantsA andB, corrected for second order hfs perturbations, could be derived from these measurements. The theoretical interpretation of these correctedA- andB-factors was performed in the intermediate coupling scheme taking into account the configurations 3d 54s 2, 3d 64s and 3d 7. Examining the influence of the composition of the eigenvectors on the hfs parameters $$\left\langle {r^{ - 3} } \right\rangle ^{k_s k_l } $$ it was found, that for the configuration 3d 64s the two-body magnetic interaction should be considered in the calculation of the eigenvectors. Investigating second order electrostatic configuration interactions and relativistic effects and using calculated relativistic correction factors we obtained for the nuclear quadrupole moment of the nucleus55Mn a value ofQ=0.33(1) barn, which is not perturbed by a shielding or antishielding Sternheimer factor. The following hfs constants have been obtained: $$\begin{gathered} A\left( {{1 \mathord{\left/ {\vphantom {1 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 882.056\left( {12} \right)MHz \hfill \\ A\left( {{3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 469.391\left( 7 \right)MHzB\left( {{3 \mathord{\left/ {\vphantom {3 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = - 65.091\left( {50} \right)MHz \hfill \\ A\left( {{5 \mathord{\left/ {\vphantom {5 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 436.715\left( 3 \right)MHzB\left( {{5 \mathord{\left/ {\vphantom {5 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = - 46.769\left( {30} \right)MHz \hfill \\ A\left( {{7 \mathord{\left/ {\vphantom {7 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 458.930\left( 3 \right)MHzB\left( {{7 \mathord{\left/ {\vphantom {7 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 21.701\left( {40} \right)MHz \hfill \\ A\left( {{9 \mathord{\left/ {\vphantom {9 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 510.308\left( 8 \right)MHzB\left( {{9 \mathord{\left/ {\vphantom {9 2}} \right. \kern-\nulldelimiterspace} 2}} \right) = 132.200\left( {120} \right)MHz \hfill \\ \end{gathered} $$

Notizen: Abstract The hyperfine structure splittings of the electronic ground statea 4 F 9/2 in the Co59-I-spectrum have been measured with a magnetic atomic-beam resonance-apparatus. From these splittings the magnetic dipole and electric quadrupole interaction constants are found to beA (a 4 F /2)=(450,284±0,01) Mc/sec,B (a 4 F 9/2)= (139,63±0,5) Mc/sec. Taking into account the mixture of thea 4 F 9/2 state with states of the same 3d 7 4s 2-electron-configuration, an electric quadrupole moment of Co59 ofQ=(0,404±0,04) 10−24 cm2 was obtained. No Sternheimer-correction has been included.

Notizen: Abstract In an atomic beam magnetic resonance experiment on Tb159 ΔF=0 transitions in several hfs-levels of thermally excited fine structure states have been observed. Detailed analysis of data showed twoJ=15/2 states, oneJ=13/2, oneJ=11/2, and, probably, oneJ=9/2 state to be present. For these levelsg J-values are given. It was concluded that the ground state of neutral terbium is 4f 8 5d 6s 2 8 G 15/2. The 4f 9 6s 2 6 H 15/2-level lies not more than 1000 cm−1 higher.