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  • 1975-1979  (2)
  • 1925-1929
  • Chemical Engineering  (2)
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  • 1
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Five glass bead-filled polypropylene composites, which had been rheologically characterized, were used in mold-filling studies to investigate the influence of rigid beads (0 to 26 vol percent) in complex flow fields. The two basic flows studied were simple shear flow in an edge-gated, rectangular cavity and stagnation flow leading to diverging radial flow in a center-gated, rectangular cavity. Pigmented tracer elements were used to illustrate flow patterns and to distinguish the skin-core structure which is a consequence of the injection molding process.Despite the strong dependence of the rheological properties (both viscous and elastic) and physical properties (density, thermal conductivity, etc.) on bead volume fraction, the basic character of the polymer dominated the flow behavior of each composite and the flow patterns were unaffected by the beads. Injection pressures were increased with increasing bead fraction to maintain the same, constant volumetric flow rate (2.21 in.3/min) for each composite. Relative injection forces follow closely the relative viscosit trend.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 17 (1977), S. 657-665 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Five glass bead-filled polypropylene composites were rheologically characterized at 240°C using two rotational rheometers to obtain low shear-rate data and a capillary rheometer to obtain high shear-rate data. Both steady and dynamic properties were measured at low shear rates. Each composite was also injection molded into tensile and flexural test bars for a mechanical properties profile at 25°C. The tensile modulus was determined from a simple extensional deformation whereas the flexural modulus was determined from a three-point-bend test.The relative shear viscosity and relative loss modulus are different nonlinear functions of the volume fraction of beads at a constant shear rate, while the relative storage modulus appears to be a linear function of bead fraction. The relative viscosity decreases with increasing shear rate and the zero shear-rate data are in very good agreement with the Guth-Gold equation.The relative tensile modulus and relative flexural modulus are each linear functions of bead fraction over the entire range of filler concentration, 0-29 vol percent. From these data it is concluded that a simple correspondence between slow viscous flow and small strain elasticity does not exist for these composites.
    Additional Material: 11 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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