ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Investigations on Diazo Compounds and Azides, XXX: C-Alkylation of (Diazomethyl)phosphoryl Compounds with EnaminesThe phosphoryl diazomethanes 1a and b react with the enamines 2a-d to form the β-amino-α-diazophosphoryl compounds 3a-f. Addition of perchloric acid and hydrogen chloride, respectively, yields the ammonium salts 4a-f. It seems to be plausible, that the alkylation reaction proceeds via the intermediates 5 and 7.
Notes:
Die Phosphoryldiazoalkane 1a und b reagieren mit den Enaminen 2a-d zu den β-Amino-α-diazophosphorylverbindungen 3a-f. Addition von Perchlorsäure bzw. Chlorwasserstoff liefert die Ammoniumsalze 4a-f. Es erscheint plausibel, daß die Alkylierungsreaktion über die Zwischenstufen 5 und 7 verläuft.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19781110624
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