ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Complete Raman data are reported for the ν1, ν6 and ν8 regions of the vibrational spectra of the C2ν deuterium-labeled pyridines and of their water complexes. Raman data are given for frequency shifts observed when some of these pyridines are dissolved in a selection of hydrogen-bonding solvents. The complicated ν8 region is afforded definitive assignment based on Fermi resonance between the A1 component of ν8 and the A1 combination tone ν1 + ν6a, as well as on the ways in which these resonances are made or broken when hydrogen-bonded complexes are formed with the deuterium-labeled pyridines.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250080314
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