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A rationalization of the enthalpy of protonation of polyamines (1979)

Barbucci, Rolando ; Barone, Vincenzo

Springer

Journal of solution chemistry 8 (1979), S. 427-438

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ISSN: 1572-8927

Keywords: Protonation of polyamines ; enthalpy ; bond formation enthalpy ; solvation enthalpy

Source: Springer Online Journal Archives 1860-2000

Topics: Chemistry and Pharmacology

Notes: Abstract The enthalpies of protonation of polyamines in aqueous solution are interpreted in terms of a simple model that does not involve any tautomeric equilibrium. The enthalpies are calculated as the sum of two contributions; bond formation enthalpy (E B ) and solvation enthalpy (E S . The results agree well with experimental data.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF00716002

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