ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
The formation of the rearrangement ions [R—O—Si(CH3)2]+ from [M - CH3]+ ions of the epimeric 5-methylcyclohexane-cis -1,3-diol-TMS ethers is independent of the 5-Me configuration, in contrast to the sterochemical effect of the 5-Me group, in the eliminations from [M]+· of related derivatives.
Notes:
Die Bildung der Silylumlagerungsionen [R—O—Si(CH3)2]+ aus [M-CH3]+-Ionen der epimeren 5- Methylcylohexan-cis-1,3-diol-TMS-äther ist unabhängig von der 5- Me-Konfiguration im Gegensatz zu den stereochmischen Effekten der 5-Me-Gruppe bei den Eliminierungen aus [M]+· verwandtr Derivate.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210101214
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