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  • 1975-1979  (2)
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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 22 (1976), S. 324-331 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model describing two consecutive gas-liquid reactors in a continously stirred-tank reactor is developed with reaction factors used to account for the interactions between the chemical and transport rate processes. A parametric numerical study revealed several interesting effects, including the existence of up to seven steady state solutions. The predictions of the model adequately describe the steady state multiplicity observed during the chlorination of liquid n-decane. It is shown that the steady state multiplicity can serve as an excellent tool for discriminating among rival models and estimation of kinetic parameters.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 21 (1975), S. 318-326 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A model of an adiabatic continuously stirred-tank reactor in which a single exothermic second order-gas liquid reaction occurs has been developed. The interactions between the rate of the chemical reaction, the diffusional resistances, and the solubility may cause the occurrence of up to five steady state solutions, even though no more than three solutions can be attained when the same reaction is carried out in a sinle phase CSTR. A parametric study is used to examine the sensitivity of the model to the value of several parameters. Topological arguments are used to obtain a simple instability criterion.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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