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  • 1975-1979  (3)
Material
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 7 (1977), S. 37-43 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract A solid electrolyte cell has been developed using a high copper ion conductivity solid electrolyte, 7CuBr·C6H12N4CH3Br, a copper anode, and a chalcogen cathode. The open-circuit voltages of the cells with sulphur, selenium, and tellurium as cathode materials were 0·448, 0·373, and 0·258 V, respectively, at 25° C. These cells yielded a current of several tens of microamperes at room temperature and several milliamperes at 114° C without appreciable polarization. An energy density of 4.5 Wh kg−1 at room temperature was evaluated from the weights of the electrolyte and electrode materials for the cell using a selenium cathode in the discharge current density range 60–150μA cm−2.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 7 (1977), S. 253-256 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The electrical conductivities of the copper (I) halide-sulphonium halide systems were measured and high conductivity copper ion conductors were found in the copper (I) iodide-1-methyl-1-thioniacyclohexane iodide (C5H10SCH3I) and copper (I) iodide-4-methyl-1, 4-oxathianium iodide (C4H8OSCH3I) systems. The dependence of electrical conductivity on the composition showed that the maximum conductivity appeared at 83.4 mol% CuI for these two systems. The highest conductivities of the systems, CuI-C5H10SCH3I and CuI-C4H8OSCH3I, were 1.4×10−3 and 7.2×10−4 (Ω cm)−1 at 25
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of applied electrochemistry 8 (1978), S. 161-164 
    ISSN: 1572-8838
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract The phase diagram of the CuCl-TlCl system has been determined by the use of differential thermal analysis, X-ray diffraction analysis and conductivity measurement. Two intermediate compounds, Tl2CuCl3 and Tl3Cu2Cl5, have been identified. Tl2CuCl3 is stable up to 204° C and above this temperature it disproportionates to TlCl and Tl3 Cu2 Cl5. Tl3 Cu2 Cl5 is stable between its incongruent melting point (210° C) and 95° C. The electrical conductivity and the transport number measurements indicate that Tl3Cu2Cl5 has a high copper ion conductivity of 2 × 10−2 (ohm cm)−1 at 100° C and Tl2CuCl3 is a poor conductor.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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