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  • 1970-1974  (4)
  • 1960-1964  (2)
  • Chemistry  (5)
  • Bone  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Calcified tissue international 6 (1970), S. 103-112 
    ISSN: 1432-0827
    Keywords: Calcium ; Strontium ; Bone ; Exchange ; Equilibrium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine , Physics
    Description / Table of Contents: Résumé La réactivité de l'os de rat envers un contenu faible et élevé de strontium a été étudiée par la technique de l'échange radioisotopique dans des conditionsin vitro bien définies. Des courbes d'absorption de solution de45Ca par des poudres d'os, pauvres et riches en strontium, ainsi que celles de solution de85Sr par des poudres d'os, riches en strontium, ont été analysées. Des fonctions exponentielles et de puissance ont été établies. Les résultats indiquent que le strontium en solution atteint un équilibre d'échange dans l'os, à contenu élevé en strontium, en huit heures environ et que le calcium continue à rechercher un état d'équilibre. Il semble, en outre, que les réactions de diffusion et d'échange de surface de la phase solide hydratée soient les mécanismes majeurs observés pendant ces expériences.
    Abstract: Zusammenfassung Die Reaktionsfähigkeit von Rattenknochen mit niederem und hohem Strontiumgehalt wurdein vitro mit der Isotopenaustauschtechnik unter gut definierten Bedingungen untersucht. Kurven, welche die vom Knochenpulver mit niederem und hohem Strontiumgehalt aufgenommene45Ca-Menge, sowie jene von Knochenpulver mit ausschließlich hohem Strontiumgehalt aufgenommene85Sr-Menge wiedergaben, wurden ausgewertet. Die Gleichungen der Exponential- sowie der Potenzfunktionen wurden abgeleitet. Die Interpretation der Ergebnisse dieser Experimente ist, daß das Strontium der Lösung ein Austauschgleichgewicht mit Knochen mit hohem Strontiumgehalt nach einer Periode von etwa 8 Std erreicht, während Calcium fortfährt, sich einem Gleichgewichtsstadium zu nähern. Es wird weiterhin vermutet, daß Diffusion und Oberflächen-Austauschreaktionen der Hydratationsschicht der soliden Phase die vorherrschenden Vorgänge sind, die im Laufe dieser Experimente stattfinden.
    Notes: Abstract The reactivity of rat bone of low- or of high-strontium content was investigated by the technique of radioisotopic exchange under well-defined conditionsin vitro. Analyses of curves depicting the uptake from solution of45Ca by low- and by high-strontium bone powders, and of85Sr by high-strontium bone powder only, were performed. Both exponential and power function expressions were derived. The interpretation of results of these experiments is that strontium of solution reaches exchange-equilibrium with bone of high-strontium content over a period of about eight hours, but that calcium continues to approach a state of equilibrium. Further, it is suggested that diffusion and surface exchange reactions of the hydrated solid phase are the dominant processes operating during the periods of these experiments.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 145-149 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The transfer rates of n-butanol, cyclohexanol, and ethyl acetate into water drops have been measured for circulating and oscillating drops.Methods of allowing for the end-effect transfer have been extended and measured values compared with predictions of a model.Various mechanisms for transfer inside drops have been examined in terms of a correlation factor.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 20 (1974), S. 966-974 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: With a Mach-Zehnder interferometer, salt concentration profiles were measured in a reverse osmosis system under natural convection with the membrane in a vertical position. The measured concentration profiles compared favorably with those predicted theoretically as long as the motion remained laminar. At large distances from the leading edge, however, the flow developed a wavy pattern, especially for bulk salt concentrations in excess of 0.1 moles/liter. As expected, whenever this motion became especially pronounced, the concentration of salt at the membrane surface was less and the production rate of fresh water greater than that predicted using the laminar analysis.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 6 (1960), S. 373-381 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The performance of sieve trays in the rectification of the methanol-water system without entrainment or leakage from the perforations was studied in an 8-in.-diameter five-tray column. The trays had a 2-in. weir height and 4-in. length of liquid path. Three tray geometries were studied: 1/4-in. diameter holes on 3/4-in. triangular spacing, 1/8-in. holes on 3/8-in. triangular spacing, and 3/16-in. on 7/16-in. triangular spacing. The superficial vapor velocity was varied from 2.2 ft./sec. to the limit of stable operation, which for this apparatus was 4.4 ft./sec. The ratio LM/VM within the column was varied from 1 to 0.5. The Murphree plate efficiency varied greatly from 105% at low concentration to 82% at high concentrations of methanol. Variations of 10 or 12 efficiency % were noted owing to changing velocities and tray geometries. Measurements of concentration gradients, foam heights, and gas pressure drops are also reported. This paper proposes a method of calculating the point efficiency and the number of individual-phase mass transfer units independent of the actual concentration gradient on the tray.The method is applied to the methanol-water data, and calculated point efficiencies range from 50 to 65%. The value of 1/NL for the methanol-water system is found to be small. The values of NG and the effect of the velocity on NG are believed to be the first in the literature for a tray in distillation operation. The effect of velocity is shown to be in agreement with the theory proposed by Gerster and co-workers. It is shown that kG' aG decreases for increasing free area and increasing hole size. Finally variation in LM/VM is shown to have little effect on EMV.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für die chemische Industrie 83 (1971), S. 116-117 
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Chemie International Edition in English 10 (1971), S. 140-141 
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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