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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 18 (1972), S. 393-401 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Liapunov analysis techniques employing a general quadratic functional are used to derive stability conditions for tubular reactor systems. The adiabatic tubular reactor without axial dispersion is shown to be locally stable, which excludes the possibility of multiple steady states, and the reactor with axial dispersion is proven locally stable if a condition involving only system parameters and steady state values is satisfied. Peclet numbers for heat and mass transfer are not specified equal for the latter proof.Results of simulation studies are used to confirm the validity of the derived stability condition, and it is shown that the parametric region of multiplicity is quite well defined. For the nonlinear equations, single steady state cases appear to possess nonuniform stability.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 14 (1970), S. 2469-2479 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The automatic endless belt polymer fractionator utilizes a continuous application and multistage extraction technique. A thin coating of polymer deposited on a slowly moving endless belt which passes through a series of solvent-nonsolvent mixtures of increasing solvent strength is fractionally dissolved. Discussion includes the description of the construction of the apparatus, details and results of fractionations of Neoprene W and polytetramethylene ether glycol, fractionation techniques and subsequent work-up of the fractions, “large scale” preparative fractionations, and general performance characteristics.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In the course of the biosynthesis of verrucarol (3) from farnesyl pyrophosphate in Myrothecium roridum, strain S 1135, a hydride shift occurs from the central double bond of the precursor to C(2) of the product.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 42 (1960), S. 119-123 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The Co-60 γ-radiation-induced polymerization of ethenesulfonamide is extremely rapid. The monomer is converted to polymer at the rate of 75%/hr. at 4200 r/min. as compared to rates of 1-17%/hr. for other monomers under similar conditions. The polymer shows the viscosity characteristics of a polyelectrolyte (intrinsic viscosity of 0.5 at 0.125% in dimethylformamide) and is estimated to have molecular weight of M̄n 12,000 and M̄w 50,000 from a preliminary evaluation of viscosity, osmotic, and light scattering data, Gi values of 170-40 are indicated for the polymerization on the basis of estimated molecular weights of 12,000-50,000.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    Journal of Polymer Science 55 (1961), S. 821-826 
    ISSN: 0022-3832
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: While it is accepted that the high-energy irradiation of poly (vinyl chloride) produces a predominately crosslinked material, confusion exists about the vinyl chloride-vinylidene chloride copolymer system. Degradation is generally assumed. We have shown that crosslinking (or endlinking) predominates over chain scission in several poly (vinyl chloride-vinylidene chloride) systems. The relative amounts of the two reactions are a function of vinylidene chloride content in the copolymer. While crosslinking is increased at increased temperatures during irradiation, and decresed in the presence of oxygen, a much larger effect is exerted by the physical form (or heat history) of the solid copolymer itself.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A: General Papers 1 (1963), S. 1927-1935 
    ISSN: 0449-2951
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The preparation of 20-40 g. quantities of sharply defined fractions of poly-α-methylstyrene, for use as standards in the correlation of molecular weight methods, is described. The procedure involves a moderately careful synthesis and fractionation. Differences in the light-scattering second virial coefficient appear to be indicative of differences in the stereoregularity of the polymers prepared by different initiators. The intrinsic viscosities of all of the polymers studied are expressed by a Mark-Houwink equation that is the same in all cases.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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