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Percus-Yevick virial relation and scaled particle theory (1974)

Ahn, Saeyoung ; Frisch, H. L.

Springer

Journal of statistical physics 11 (1974), S. 283-289

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ISSN: 1572-9613

Keywords: Scaled particle theory ; hard sphere fluids

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract The conditional probability of finding a cavityG(r) devoid of molecular centers of hard sphere fluid is modified by making use of the discontinuity atr=a/2 (a is the diameter of a molecule). The new equation of state thus obtained is bounded by the Percus-Yevick compressibility and virial pressure equations of state, which may be the upper and lower bounds to the results of machine calculation.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01009789

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