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  • 1970-1974  (2)
  • 1955-1959
  • Analytical Chemistry and Spectroscopy  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Etude par RMN de la Structure des Cyano-2 Alcoyl-2 Norbornenes-5 (1970)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 2 (1970), S. 71-78 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Interpretation of the NMR spectra of the isomeric 2-cyano-2-alkyl-5-norbornenes allowed the assignment of their respective structures. In the case of the 2-cyano-2-methyl-5-norbornene the structure assignment was confirmed by chemical synthesis (alkaline hydrolysis and iodo-lactonisation).
    Notes: L'attribution de structure des deux isomères cyano-2 alcoyl-2 norbornène-5 est possible grǎce aux données de la RMN. Une interprétation des spectres de ces dérivés bicycliques set donnée. Dans le cas des cyano-2 méthyl-2 norbornènes-5 une confirmation de structure a pu ětre donnée par voie chimique (hydrolyse basique et iodolactonisation).
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270020109
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Etude du couplage 2J(N15—H) en série hétérocyclique. Application à la détermination des constantes d'équilibres prototropiques rapides (1974)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 6 (1974), S. 224-225 
    Details
    ISSN: 0030-4921
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: The fast tautomeric equilibrium of (N15)-4-phenylisoxazolin-5-one (2) has been investigated by a study of 2J(N15—H3) coupling. Comparison of the observed values for 2 and for the two fixed forms (N15)-2-methyl-4-phenylisoxazolin-5-one (3) and (N15)-4-phenyl-5-methoxyisoxazol (4) indicates a considerable amount of enolic type structure for 2 in basic media.
    Notes: La comparasion des constantes de couplage 2J(N15—H3) présentées par la (N15)-4-phénylisoxazoline-5-one (2) et par deux de ses formes fixes, la (N15)-2-méthyl-4-phénylisoxazoline-5-one (3) et le (N15)-4-phényl-5-méthoxyisoxazole (4), indique une participation élevée de structure énolique (et/ou ionique) dans les milieux basiques.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1270060408
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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