ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Rearrangement of the molecular ions of tetracyclone, tetraphenylquinone, tetraphenylthiophene dioxide and pentaphenylcyclopentadienol prior to decomposition, rather than formation of a symmetrical [C4Ar4]+· ion, is considered as an alternative method for the production of [C2Ar2]+·. The p-fluoro substituent is used to elicit information about the positional origins of the [C2Ar2]+· fragments. Operation of a double focusing mass spectrometer in the defocused mode reveals that the integrity of the molecular ion in different systems is affected to varying degrees, ranging from total lack of rearrangement to virtually complete scrambling.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210030707
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