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  • 1
    Electronic Resource
    Electronic Resource
    Source of the carboxamide nitrogen atom in 2-carboxamido-5-isopropoxycarbonylaminobenzimidazole, a metabolite of cambendazole (1974)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 1 (1974), S. 190-191 
    Details
    ISSN: 1052-9306
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Combined gas chromatography-mass spectrometry and isotope labeling techniques have been employed to demonstrate that the carboxamide nitrogen atom in 2-carboxamido-5-isopropoxycarbonylaminobenzimidazole, a metabolite of 2-thiazolyl-5-isopropoxycarbonylaminobenzimidazole (cambendazole), is derived wholly from the parent drug. [15N] Thiazole-labeled cambendazole was administered to a rat and the metabolite isolated from urine. Trideutero-2-carboxamido-5-isopropoxycarbonylaminobenzimidazole was employed as a carrier to isolate the metabolite in sufficient purity for isotope ratio measurements using multiple ion detection. The metabolite was converted to its tetramethyl derivative by on-column reaction with trimethylanilium hydroxide to permit satisfactory gas chromatography.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/bms.1200010308
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  • 2
    Electronic Resource
    Electronic Resource
    Zum Ionenaustausch in porösen Gläsern (1974)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 408 (1974), S. 237-246 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Ionexchange on Porous GlassesPorous alkali-boron-silicate glasses show the following sequence of coefficients of the ionexchange-selectivity: \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm Ti}^{\rm + } 〉 {\rm Ag}^{\rm + } 〉 {\rm K}^{\rm + } 〉 {\rm Na}^{\rm + } 〉 {\rm Li}^{\rm + } . $$\end{document} The degree of ionexchange for divalent ions is only very little. The ionexchange capacity is influenced by the degree of phase-separation of the original glasses and has the origin in BOH groups. The energies of activation for the ionexchange reactions are 10.6-11.8 kcal/mol.
    Notes: An porösen Alkali-Bor-Silikatgläsern konnte folgende Abstufung der Ionenaustausch-Selektivitätskoeffizienten ermittelt werden: \documentclass{article}\pagestyle{empty}\begin{document}$$ {\rm Ti}^{\rm + } 〉 {\rm Ag}^{\rm + } 〉 {\rm K}^{\rm + } 〉 {\rm Na}^{\rm + } 〉 {\rm Li}^{\rm + } . $$\end{document} Der Ionenaustausch für 2wertige Ionen ist nur gering. Die Ionenaustauschkapazität läßt sich auf den Grad der Phasentrennung in den Ausgangsgläsern zurückführen und beruht auf dem Vorhandensein von BOH-Gruppen. Die Aktivitätsenergien für die Ionenaustausch-Reaktionen liegen zwischen 10,6-11,8 kcal/Mol.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19744080303
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  • 3
    Electronic Resource
    Electronic Resource
    Zur chemisch-thermischen Modifizierung von Kieselgel mit B2O3 (1972)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 393 (1972), S. 50-58 
    Details
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: On the chemically thermal modification of gelatinous silica with B2O3The chemically thermal modification of gelatinous silica with boron oxide was studied in dependence on the quantity of impregnated boron oxide, on time, and temperature of the treatment. A. condensation mechanism is discussed on the basis of structure variation of the modification samples.
    Notes: Die chemisch-thermische Modifizierung von Kieselgel mit Boroxid wurde untersucht in Abhängigkeit von der Menge an aufgetränktem Boroxid, von der Zeit und der Temperatur der Thermobehandlung. Ein Kondensationsmechanismus wird im Zusammenhang mit Strukturveränderungen diskutiert.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19723930106
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  • 4
    Electronic Resource
    Electronic Resource
    Vergleichende Untersuchungen an temperaturbeständigen Pigmenten auf Basis 3-Amino-phthalsäureimid. I (1971)
    New York, NY : Wiley-Blackwell
    Journal für Praktische Chemie/Chemiker-Zeitung 313 (1971), S. 301-308 
    Details
    ISSN: 0021-8383
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Es wurden hochtemperaturbeständige Azopigmente auf der Basis von 3-Amino-phthalsäureimid hergestellt. Durch Einführung von Chlorsubstituenten konnte die Lichtechtheit günstig beeinflußt werden. Die Migrationsechtheit wurde durch Molekülverdopplung entscheidend verbessert.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/prac.19713130215
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    Paper (German National Licenses)
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