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Digitale Medien

Conformation and hydration of sugars and related compounds in dilute aqueous solution (1973)

franks, F. ; Reid, D. S. ; Suggett, A.

Springer

Journal of solution chemistry 2 (1973), S. 99-118

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ISSN: 1572-8927

Schlagwort(e): Heats of solution ; heat capacity ; dipole moments ; static permittivity ; carbohydrates ; dielectric relaxation ; sugar conformation ; alcohols

Quelle: Springer Online Journal Archives 1860-2000

Thema: Chemie und Pharmazie

Notizen: Abstract The effect of hydroxyl substitution on the nature of the hydration of an alkane chain has been studied by calorimetric techniques. Static permittivities (ɛ0) of a range of monosaccharides and related compounds in aqueous solution have also been determined. The (ɛ0) data, suitably processed, have provided information about the solute dipole moments. In conjunction with earlier results from volumetric, compressibility, and relaxation studies, the specific hydration model is further developed and the relationships between solute molecular conformations and solute-water interactions are discussed.

Materialart: Digitale Medien

URL: http://dx.doi.org/10.1007/BF00651968

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