ISSN:
1572-8927
Keywords:
Cation
;
energies
;
H. S. Frank
;
M. Eigen
;
R. G. Wilkins
;
kinetics
;
ligand substitution
;
mechanism
;
mixed solvents
;
nonaqueous
;
solvation
;
solvent
;
solvent structure
;
solvent exchange
;
transition metal
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The role of the solvent in reactions involving ions is considered in relation to the structure of liquids. The rate constants and activation parameters for ligand substitutions at divalent transition metal cations in various solvents are compared with those for solvent exchanges. The differences are related to structural properties of the solvents, represented by their heats of evaporation and fluidities, and interpreted with the aid of a model developed from that of Frank and Wen. Water is not a typical solvent.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00651974
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