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  • 1970-1974  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 398 (1973), S. 249-256 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Synthesis and Properties of W(CH3COO)2.W(Ac)2 is reported for the first time. IR- and UV-spectroscopic investigations give indications concerning the structure of the compound. The IR-spectrum shows the bridging function of the acetate group. From the UV-spectrum the presence of a W—W bond is derived. Investigations of vapourization (mass spectrometer) and the behaviour in solution are explained by a polymeric structure
    Notes: W(Ac)2 wurde neu dargestellt. IR- und UV-spektroskopische Untersuchungen geben Hinweise auf die Struktur der Verbindung. Das IR-Spektrum läßt die bidentale Funktion der Acetat-Gruppe erkennen. Das UV-Spektrum zeigt das Vorliegen einer W—W-Bindung. Massenspektrometrische Untersuchungen und Lösungsverhalten deuten auf eine polymere Struktur hin.
    Additional Material: 5 Tab.
    Type of Medium: Electronic Resource
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