ISSN:
1573-9171
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Conclusions 1. Chiefly Mo4+ ions are responsible for the chemisorption of oxygen at 25°. 2. The adsorption of oxygen at 25° leads to the formation of an O2 − ion radical, stabilized at the cation of the lattice of the carrier. 3. Stabilization of the ion radical O2 − at applied Mo ions is possible only at lower temperatures. 4. The transfer of an electron from an applied Mo5+ or Mo4+ ion through the lattice of the carrier seems relatively improbable in the case of Al2O3, while in the case of MgO only the ions of the lattice that are the closest neighbors of molybdenum participate in this process.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00851246
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