ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
In 2,6-di-unsaturated carbonyl compounds, two successive, site-specific hydrogen transfers are necessary to account for the loss of carbon atoms 1, 2, 3 and 4, together with one hydrogen from C-8. The deuterated methyl geranate required for this study was readily converted to pseudo-ionone, in which a similar fission was shown to occur. Previous predictions about the β-ionone mass spectrum2 have been shown to be substantially correct, and its similarity to the mass spectra of benzylidence acetones is pointed out.
Additional Material:
8 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210020208
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