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Derivatives of cyclotetrazenoborane (tetrazoborol-2-ine) - VI.1 Mass spectra of B substituted cyclotetrazenoboranes (1968)

Brittain, E. F. H. ; Leach, J. B. ; Morris, J. H.

Chichester : Wiley-Blackwell

Biological Mass Spectrometry 1 (1968), S. 459-465

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ISSN: 0030-493X

Keywords: Chemistry ; Analytical Chemistry and Spectroscopy

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The mass spectra of B substituted 2,5-dimethyl cyclotetrazenoboranes have been studied. The compounds Me2N4BD, Me2N4BEt, Me2N4BVi, Me2N4BCl and Me2N4BBr give confirmatory evidence that loss of N2+H. from the system occurs by loss of H from the side chain and that the B—R bond is very stable under electron impact conditions. Fragmentation proceeds in a similar fashion to that of the 2,5-dimethyl substituted compounds with H bonded to the boron atom.

Additional Material: 5 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/oms.1210010313

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