ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The diphenol 1 was resolved into its antipodes and their absolute configuration was established. The levorotatory isomer R-(-)-1 was oxidized to the dienone R-(-)-6, which was rearranged to afford natural (-)-multifloramine (R-(-)-7), thus establishing that the latter has the R-configuration. By the same reaction sequences, the enantiomeric diphenol S-(+)-1 was transformed to provide (+)-multifloramine (S-(+)-7) of the S-configuration.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19690520316
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