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  • 1965-1969  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Generation of free radicals at subzero temperatures. III. Polyamine-hydroperoxide-iron system (1969)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 7 (1969), S. 735-741 
    Details
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The mechanism of the reaction of tetraethylenepentamine (TEPA) with cumene hydroperoxide (CHP) and iron ions was investigated. It was found that (1) TEPA did not reduce Fe(III); (2) TEPA was consumed by this reaction; (3) both Fe(II) and Fe(III) were effective for this reaction. It was shown that though the O—O bond of a hydroperoxide could be cleaved only at elevated temperatures, it could be easily cleaved by the reaction with the iron-TEPA complex. The function of this iron-TEPA complex is discussed.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1969.150070226
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