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  • 1965-1969  (2)
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  • 1
    Digitale Medien
    Digitale Medien
    Fundamentals of plasticating extrusion. II. Experiments (1966)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 6 (1966), S. 191-197 
    Details
    ISSN: 0032-3888
    Schlagwort(e): Chemistry ; Chemical Engineering
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Experiments were performed to develop quantitative information for designing plasticating extruders for low density polyethylene. Screw design variables explored included feed section length, compression section taper, and minimum channel depth. Operating variables included were screw speed, barrel temperature, and back pressure. A moving picture film illustrates temperature action and cross-channel temperature distribution for some typical experiments using a new type of extruder screw for 2.5 inch and 8 inch diameter extrusion. The information gathered was used to obtain relations between performance and screw dimensions and revealed an optimum combination of feed section length and compression taper.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/pen.760060304
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  • 2
    Digitale Medien
    Digitale Medien
    Properties of semicrystalline polyolefins. II. Copolymers of 3-methyl-1-pentene and 4-methyl-1-pentene (1965)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 9 (1965), S. 933-940 
    Details
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A study of the copolymerization of 3-methyl-1-pentene (3-MP) and 4-methyl-1-pentene (4-MP) showed that the poly-4-MP crystal lattice is capable of incorporating large quantities of 3-MP without a sharp lowering of melting point or adverse effect on physical and mechanical properties. The reactivity ratio of the two monomers in copolymerization are r(4-MP) = 6.2 ± 0.2 and r(3-MP) = 0.1 ± 0.1. As a result, mixed feeds containing up to 80% 3-MP produce copolymers composed primarily of repeating 4-MP units, with a random insertion of 3-MP monomer units. Calculations indicate that in a copolymer containing 37% 3-MP, the probability of finding a sequence of 2 units of 3-MP is only a little better than 5%. This copolymer shows a somewhat increased resistance to deformation under load than homopoly 4-MP. Its crystalline melting point is 248°C.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
    URL: http://dx.doi.org/10.1002/app.1965.070090311
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