ISSN:
0449-296X
Keywords:
Physics
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
When crystals of N-vinylcarbazole are γ-irradiated at 77°K., the ESR spectrum observed before warming consists of three peaks attributed to a radical-cation with the unpaired spin associated mainly with the nitrogen atom. Above 90°K. polymerization occurs, initiated by the cation, and the spectrum changes to that of an alkyl type of radical, =N—ĊH—CH2, trapped in the polymer. Single crystals were used for a detailed analysis of the nuclear hyperfine parameters of the observed radicals.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1968.150060522
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