ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Ultra-violet irradiation of 1-dehydro-2-formyl-testosterone acetate (1) in dioxane leads to a complex mixture containing the salicylic aldehyde derivative 2 as the major component. Traces of 2-methyl-4-hydroxy-17β-acetoxy-Δ1;3,5,10-estratriene have also been isolated. Acid-catalysed dienone-phenol rearrangement of 1 yields a phenol (6) of the same structure type as the major photoproduct 2.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19630460733
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