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Molecular configuration of polystyrene in benzene (1963)

Debye, P. ; Chu, B. ; Kaufmann, H.

New York : Wiley-Blackwell

Journal of Polymer Science Part A: General Papers 1 (1963), S. 2387-2394

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ISSN: 0449-2951

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The particle scattering factor P(ϑ) with Gaussian statistics for polydispersed systems has been treated. For a polystyrene sample with a sharp molecular weight distribution (Mw/Mn 〈 1.02, Mw = 1.5 X 106), the measured angular dependence of scattered intensity indicates that the polymer coil does obey Gaussian statistics. This holds for a range of concentrations provided the variation of the constant representing the radius of gyration with concentration is adjusted.

Additional Material: 3 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/pol.1963.100010716

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