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Influence des substituants sur la vitesse de racémisation des cétones à carbone dissymétrique en alpha (1960)

Mills, A. K. ; Smith, A. E. Wilder

New York, NY : Wiley-Blackwell

Helvetica Chimica Acta 43 (1960), S. 1915-1927

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ISSN: 0018-019X

Keywords: Chemistry ; Organic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: The rates of racemisation, under constant conditions of pH and temperature, of two series of ketones with an asymmetric C-atom in α have been determined. As would be expected, substituents in the α position to the keto group influence the rate of racemisation, and it has been found possible to assess the relative electron donating or electron attracting effect of aliphatic, aliphatic-aromatic or aromatic substituents by measuring their influence on the rate of racemisation of a ketone containing the substituent considered.

Additional Material: 2 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/hlca.19600430705

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