ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
The only observable reaction of the p-toluene sulfonates of six mono- and bicyclic α-aminoketoximes (2d-7d) is fragmentation to carbimonium salts (8-13). The fragmentation product of 1-keto-octahydropyrrocolineoxime-tosylate (6d), viz. the carbimonium salt (12), undergoes spontaneous ring closure to 2-oxo-1-azaquinolizidine (26). The intermediate (12) in this fragmentation-recombination reaction can be intercepted by cyanide ion, yielding β(2-cyano-piperid-l-yl)-propionnitrile (29 a).
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19630460415
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